The Device-Package Combination table is correct. The cause of the fewer available I/Os is that the LX75T adds another pair of GTP_DUAL at the bottom of the device. The LX45T has two GTP_DUAL, and the LX75T has four.Those additional two GTP_DUALs take away available I/O.The Spartan-6 devices use derived die technology; see
(Xilinx Answer 34394), so the added GTP_DUALs have an impact on the LX devices, even though they do not use the GTPs.