The maximum conversion rate of the System Monitor is still 200 ksPs because the ADCCLK is still 5.2 MHz.
The ADCCLK = DCLK / DCLK Divisior (the DCLK divisor is set in the Config Reg #2).
The effect of violating the maximum DCLK of 80 MHz is that it can result in a race condition in the System Monitor logic which results in incorrect readings. The problem occurs at temperatures between 55 C and 80 C only.