ISE
Printing a File
You can print files from Project Navigator as follows.
Note When printing schematics, there are additional printing options, as described in Printing a Schematic.
To Print
  1.  Select File > Print Preview to make sure the file will print as you expect.
  2.  Click Close.
  3.  Select File > Print, or click the Print toolbar button Image.
  4.  In the Print dialog box, set the Print Range to All, or specify the sheet numbers to print. You can also print the current selection or current page.
  5.  Optional. In the Print dialog box, click the Preferences button to set printer-specific settings, such as paper size and orientation.
  6.  Click Print.

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